N-(2-Chlorobenzoyl)-N′-(3-pyridyl)thiourea
نویسندگان
چکیده
In the mol-ecule of the title compound, C(13)H(10)ClN(3)OS, the dihedral angles between the plane through the thio-urea group and the pyridine and benzene rings are 53.08 (3) and 87.12 (3)°, respectively. The mol-ecules are linked by inter-molecular N-H⋯N hydrogen-bonding inter-actions to form a supra-molecular chain structure along the a axis. An intra-mol-ecular N-H⋯O hydrogen bond is also present.
منابع مشابه
1-(2-Chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea
The dihedral angle between the two phenyl groups in the title compound, C16H15ClN2OS, is 14.88 (4)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, pairs of N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.
متن کامل1-(2-Chlorobenzoyl)-3-(2-trifluoromethylphenyl)thiourea
The dihedral angle between the benzene rings in the title compound, C15H10ClF3N2OS, is 54.02 (4)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into inversion dimers.
متن کامل1-(2-Chlorobenzoyl)-3-(pyrimidin-2-yl)thiourea
In the title compound, C12H9ClN4OS, the carbonyl group is at a cis position with respect to the thio-urea unit. The dihedral angle between the phenyl and pyrimidine ring is 16.49 (6)°. An intra-molecular N-H⋯N hydrogen bond stabilizes the mol-ec-ular conformation. In the crystal, N-H⋯N, C-H⋯O and C-H⋯S hydrogen bonds generate chains along the bc axis.
متن کامل1-(2-Chlorobenzoyl)-3-(3-methoxyphenyl)thiourea
The title compound, C15H13ClN2O2S, exists in the solid state in its thione form with typical thio-urea C-S and C-O bonds lengths as well as shortened C-N bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation. In the crystal, N-H⋯S hydrogen bonds link the mol-ecules into centrosymmetric dimers.
متن کاملN-(4-Chlorobenzoyl)-N′-(3-fluorophenyl)thiourea
In the title compound, C(14)H(10)ClFN(2)OS, the mol-ecule adopts a trans-cis geometry of the thio-urea unit. The dihedral angles between the benzene rings is 34.47 (7)°. The crystal packing features inter-molecular N-H⋯S and C-H⋯O hydrogen bonds, forming a chain along the b axis. A short C-H⋯S intramolecular contact is also observed.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008